CA2216853A1 - Novel (co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization - Google Patents

Novel (co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization

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Publication number
CA2216853A1
CA2216853A1 CA002216853A CA2216853A CA2216853A1 CA 2216853 A1 CA2216853 A1 CA 2216853A1 CA 002216853 A CA002216853 A CA 002216853A CA 2216853 A CA2216853 A CA 2216853A CA 2216853 A1 CA2216853 A1 CA 2216853A1
Authority
CA
Canada
Prior art keywords
polymerization
polymers
radical polymerization
novel
atom transfer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002216853A
Other languages
French (fr)
Other versions
CA2216853C (en
Inventor
Krzysztof Matyjaszewski
Jin-Shan Wang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Carnegie Mellon University
Original Assignee
Krzysztof Matyjaszewski
Jin-Shan Wang
Carnegie Mellon University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Krzysztof Matyjaszewski, Jin-Shan Wang, Carnegie Mellon University filed Critical Krzysztof Matyjaszewski
Priority to CA002510397A priority Critical patent/CA2510397C/en
Publication of CA2216853A1 publication Critical patent/CA2216853A1/en
Application granted granted Critical
Publication of CA2216853C publication Critical patent/CA2216853C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/40—Redox systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst

Abstract

A new polymerization process (atom transfer radical polymerization, or ATRP) based on a redox reaction between a transition metal (e.g., Cu(I)/CU(II)), provides "living" or controlled radical polymerization of styrene, (meth)acrylates, and other radically polymerizable monomers. Using various simple organic halides as model halogen atom transfer precursors (initiators) and transition metal complexes as a model halogen atom transfer promoters (catalysts), a "living" radical polymerization affords (co)polymers having the predetermined number average molecular weight by .DELTA.[M]/[I]o (up to M n > 10 5) and a surprisingly narrow molecular weight distribution (M w/M n), as low as 1.15.
The participation of free radical intermediates in ATRP is supported by end-group analysis and stereochemistry of the polymerization. In addition, polymers with various topologies (e.g., block, random, star, end-functional and in-chain functional copolymers [for example, of styrene and methyl (meth)acrylate]) have been synthesized using the present process. The polymeric products encompassed by the present invention can be widely used as plastics, elastomers, adhesives, emulsifiers, thermoplastic elastomers, etc.
CA002216853A 1995-03-31 1996-03-19 Novel (co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization Expired - Lifetime CA2216853C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA002510397A CA2510397C (en) 1995-03-31 1996-03-19 Novel (co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/414,415 US5763548A (en) 1995-03-31 1995-03-31 (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
US08/414,415 1995-03-31
PCT/US1996/003302 WO1996030421A1 (en) 1995-03-31 1996-03-19 Novel (co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CA002510397A Division CA2510397C (en) 1995-03-31 1996-03-19 Novel (co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization

Publications (2)

Publication Number Publication Date
CA2216853A1 true CA2216853A1 (en) 1996-10-03
CA2216853C CA2216853C (en) 2005-10-25

Family

ID=23641358

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002216853A Expired - Lifetime CA2216853C (en) 1995-03-31 1996-03-19 Novel (co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization

Country Status (14)

Country Link
US (4) US5763548A (en)
EP (2) EP0817806B1 (en)
JP (1) JP3040172B2 (en)
KR (2) KR100282757B1 (en)
CN (2) CN1515599A (en)
AT (1) ATE317405T1 (en)
AU (1) AU720512B2 (en)
BR (1) BR9604887A (en)
CA (1) CA2216853C (en)
DE (1) DE69635802T2 (en)
IL (1) IL117626A (en)
MX (2) MX244246B (en)
TW (2) TW520380B (en)
WO (1) WO1996030421A1 (en)

Families Citing this family (542)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2730241B1 (en) * 1995-02-07 1997-02-28 Atofina PROCESS FOR MANUFACTURING A COMPOSITION COMPRISING A VINYLAROMATIC POLYMER AND A RUBBER BY POLYMERIZATION IN THE PRESENCE OF A FREE STABLE RADICAL
US6541580B1 (en) * 1995-03-31 2003-04-01 Carnegie Mellon University Atom or group transfer radical polymerization
US5763548A (en) * 1995-03-31 1998-06-09 Carnegie-Mellon University (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
US5807937A (en) † 1995-11-15 1998-09-15 Carnegie Mellon University Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties
JP3806475B2 (en) 1996-02-08 2006-08-09 株式会社カネカ Method for producing (meth) acrylic polymer having functional group at terminal
ATE207082T1 (en) 1996-06-12 2001-11-15 Univ Warwick POLYMERIZATION CATALYST AND PROCESS
DE69710130T2 (en) * 1996-06-26 2002-08-29 Kaneka Corp Process for the production of vinyl polymers
US5789487A (en) * 1996-07-10 1998-08-04 Carnegie-Mellon University Preparation of novel homo- and copolymers using atom transfer radical polymerization
FR2752238B1 (en) * 1996-08-12 1998-09-18 Atochem Elf Sa METHOD FOR CONTROLLED RADICAL POLYMERIZATION OR COPOLYMERIZATION OF (METH) ACRYLIC AND VINYLIC MONOMERS AND (CO) POLYMERS OBTAINED
US5910549A (en) 1996-08-22 1999-06-08 Carnegie-Mellon University Method for preparation of alkoxyamines from nitroxyl radicals
US20030198825A1 (en) * 1996-08-26 2003-10-23 Massachusetts Institute Of Technology Polymeric membranes and other polymer articles having desired surface characteristics and method for their preparation
US5852129A (en) 1996-11-28 1998-12-22 Kaneka Corporation Method for producing hydroxyl-terminated (meth) acrylic polymer
GB2321247A (en) * 1997-01-20 1998-07-22 Courtaulds Plc Polymerisation reactions
TW593347B (en) * 1997-03-11 2004-06-21 Univ Carnegie Mellon Improvements in atom or group transfer radical polymerization
US7125938B2 (en) * 1997-03-11 2006-10-24 Carnegie Mellon University Atom or group transfer radical polymerization
US5886118C1 (en) * 1997-04-14 2001-02-20 Univ Case Western Reserve Process for polymerizing acrylonitrile
US6423787B1 (en) * 1997-04-18 2002-07-23 Kaneka Corporation Polymers, processes for producing the same, and curable compositions produced therefrom
US6074628A (en) * 1997-04-25 2000-06-13 Procter & Gamble Hairspray compositions containing silicon block copolymers
US6113883A (en) * 1997-04-25 2000-09-05 The Procter & Gamble Company Hair styling compositions comprising silicone-containing copolymers
US6136296A (en) * 1997-04-25 2000-10-24 The Procter & Gamble Company Personal care compositions
US5986015A (en) * 1997-05-16 1999-11-16 The Procter & Gamble Company Method of making graft polymers
ZA984087B (en) * 1997-05-16 1998-11-16 Procter & Gamble Personal care compositions containing graft polymers
US6274688B1 (en) * 1997-07-28 2001-08-14 Kaneka Corporation Functional groups-terminated vinyl polymers
US6552118B2 (en) 1997-07-28 2003-04-22 Kaneka Corporation Curable adhesive composition
EP1000954B1 (en) * 1997-07-28 2006-08-23 Kaneka Corporation Polymers and process for producing polymers
US6720395B2 (en) * 1997-07-28 2004-04-13 Kaneka Corporation Method for producing a stellar polymer
EP1002847B8 (en) 1997-08-06 2015-06-03 Kaneka Corporation Self-adhesive composition
US6071980A (en) * 1997-08-27 2000-06-06 E. I. Du Pont De Nemours And Company Atom transfer radical polymerization
EP1024153B1 (en) * 1997-09-22 2005-02-16 Kaneka Corporation Polymer, process for producing the polymer, and curable composition containing the polymer
US6069205A (en) * 1997-10-03 2000-05-30 Eastman Kodak Company Block copolymers
US6143848A (en) 1997-10-23 2000-11-07 The B.F.Goodrich Company End-functionalized polymers by controlled free-radical polymerization process and polymers made therefrom
FR2770219A1 (en) * 1997-10-24 1999-04-30 Atochem Elf Sa PROCESS FOR THE MANUFACTURING OF ARCHITECTURALLY CONTROLLED COPOLYMERS USING FUNCTIONAL RADICAL PRIMERS IN LIVE RADICAL POLYMERIZATION, AND CORRESPONDING PRIMER COMPOUNDS AND COPOLYMERS
US6121380A (en) 1997-11-06 2000-09-19 Nitto Denko Corporation Preparation of adhesive (CO) polymers from isocyanate chain extended narrow molecular weight distribution telechelic (CO) polymers made by pseudo living polymerization
GB9725455D0 (en) 1997-12-02 1998-01-28 Univ Warwick Supported polymerisation catalyst
CN1152061C (en) 1998-02-27 2004-06-02 钟渊化学工业株式会社 Polymer and curable composition
JP4176900B2 (en) * 1998-02-27 2008-11-05 株式会社カネカ Curable composition
DE19813353A1 (en) * 1998-03-26 1999-09-30 Bayer Ag Processes for the production of telecheles, telecheles thus produced and their use
EP1085027B1 (en) 1998-03-27 2004-11-03 Kaneka Corporation Polymer and process for producing polymer
US6121371A (en) * 1998-07-31 2000-09-19 Carnegie Mellon University Application of atom transfer radical polymerization to water-borne polymerization systems
EP0947527A1 (en) * 1998-04-03 1999-10-06 The B.F. Goodrich Company Waterborne block copolymers and process for making the same
JP3776626B2 (en) * 1998-04-27 2006-05-17 株式会社カネカ Saturated hydrocarbon polymer having a functional group at its terminal and method for producing the same
JP4057190B2 (en) * 1998-04-28 2008-03-05 株式会社カネカ Block copolymer
CA2294731C (en) 1998-04-28 2008-04-01 Kaneka Corporation Block copolymer
AUPP337298A0 (en) 1998-05-07 1998-05-28 University Of Melbourne, The Process for microgel preparation
GB9809926D0 (en) * 1998-05-08 1998-07-08 Bp Chem Int Ltd Catalyst and polymerisation process
DE69930253T2 (en) 1998-06-01 2006-12-07 Kaneka Corp. METHOD FOR PRODUCING POLYMER, POLYMER AND HARDENABLE COMPOSITION CONTAINING THE POLYMER
CA2333926A1 (en) 1998-06-01 1999-12-09 Kaneka Corporation Method to control atom transfer radical polymerization
EP0962473A1 (en) * 1998-06-04 1999-12-08 Dsm N.V. Block polymer and powder-paint binder composition
DE69935259T2 (en) 1998-06-19 2007-10-25 Kaneka Corp. PROCESS FOR PREPARING BRANCHED POLYMER
EP0970972A1 (en) * 1998-07-10 2000-01-12 Ciba SC Holding AG Polymerizable composition containing Ru(II)-or Os(II)-complex catalysts
US6252025B1 (en) 1998-08-11 2001-06-26 Eastman Kodak Company Vinyl hyperbranched polymer with photographically useful end groups
US6479584B1 (en) 1998-08-20 2002-11-12 Kaneka Corporation Resin composition, polymer, and process for producing polymer
US6660399B1 (en) 1998-08-20 2003-12-09 Kaneka Corporation Composition for roller and roller therefrom
DE69939949D1 (en) * 1998-08-20 2009-01-02 Kaneka Corp POLYMER AND EPOXY RESIN COMPOSITIONS
US6306965B1 (en) 1998-08-31 2001-10-23 Ppg Industries Ohio, Inc. Thermosetting compositions containing carbamate-functional polylmers prepared using atom transfer radical polymerization
US6365666B1 (en) 1998-08-31 2002-04-02 Ppg Industries Ohio, Inc. Electrodepositable coating compositions comprising onium salt group-containing polymers prepared by atom transfer radical polymerization
US6265489B1 (en) 1998-08-31 2001-07-24 Ppg Industries Ohio, Inc. Thermosetting compositions containing carboxylic acid functional polymers prepared by atom transfer radical polymerization
US6191225B1 (en) 1998-08-31 2001-02-20 Ppg Industries Ohio, Inc. Thermosetting compositions containing carboxylic acid functional polymers and epoxy functional polymers prepared by atom transfer radical polymerization
US6268433B1 (en) 1998-08-31 2001-07-31 Ppg Industries Ohio, Inc. Thermosetting compositions containing epoxy functional polymers prepared by atom transfer radical polymerization
US6319987B1 (en) 1998-08-31 2001-11-20 Ppg Industries Ohio, Inc. Thermosetting compositions containing hydroxyl-functional polymers prepared using atom transfer radical polymerization
US6355729B1 (en) 1998-08-31 2002-03-12 Ppg Industries Ohio, Inc. Electrodepositable coating compositions comprising amine salt group-containing polymers prepared by atom transfer radical polymerization
US6319967B1 (en) 1998-08-31 2001-11-20 Ppg Industries Ohio, Inc. Thermosetting compositions containing epoxy-functional polymers prepared using atom transfer radical polymerization
US6339126B1 (en) * 1998-08-31 2002-01-15 Ppg Industries Ohio, Inc. Thermosetting compositions containing carboxylic acid functional polymers prepared by atom transfer radical polymerization
US6319988B1 (en) 1998-08-31 2001-11-20 Ppg Industries Ohio, Inc. Thermosetting compositions containing hydroxy functional polymers prepared by atom transfer radical polymerization
EP1153942B1 (en) * 1998-09-02 2006-11-08 Kaneka Corporation Polymer, processes for producing polymer, and composition
JP4015327B2 (en) * 1998-09-02 2007-11-28 株式会社カネカ Polymer, polymer production method and composition
WO2000020498A1 (en) 1998-10-08 2000-04-13 Kaneka Corporation Curable compositions
US6137012A (en) 1998-10-13 2000-10-24 E. I. Du Pont De Nemours And Company Phosphole and diphosphole ligands for catalysis
JP3984381B2 (en) * 1998-12-08 2007-10-03 株式会社カネカ Method for producing star polymer
JP4572006B2 (en) * 1998-12-08 2010-10-27 日東電工株式会社 Adhesive composition, method for producing the same, and adhesive sheet
GB9827080D0 (en) * 1998-12-10 1999-02-03 Ici Ltd Production of vinylic polymers
US6162578A (en) * 1998-12-18 2000-12-19 Eastman Kodak Company Imaging member containing heat sensitive hyperbranched polymer and methods of use
US6734256B1 (en) * 1998-12-29 2004-05-11 3M Innovative Properties Company Block copolymer hot-melt processable adhesives, methods of their preparation, and articles therefrom
AU2097799A (en) * 1998-12-29 2000-07-31 Minnesota Mining And Manufacturing Company Block copolymer hot-melt processable adhesives, methods of their preparation, and articles therefrom
KR100642674B1 (en) * 1998-12-31 2006-11-10 시바 스폐셜티 케미칼스 홀딩 인코포레이티드 Pigment composition containing atrp polymers
EP1158006B1 (en) * 1999-01-28 2006-11-15 Kaneka Corporation Polymer, process for producing the polymer, and curable composition containing the polymer
GB9902564D0 (en) * 1999-02-08 1999-03-24 Ici Plc Production of vinylic polymers
US6472486B2 (en) 1999-03-09 2002-10-29 Symyx Technologies, Inc. Controlled stable free radical emulsion polymerization processes
EP1637550B1 (en) * 1999-03-23 2017-09-20 Carnegie Mellon University Catalytic processes for the controlled polymerization of free radically (co) polymerizable monomers and functional polymeric systems prepared thereby
JP5264030B2 (en) * 1999-03-23 2013-08-14 カーネギー−メロン ユニバーシティ Catalytic process for the controlled polymerization of free-radically (co) polymerizable monomers and functional polymer systems produced thereby
DE19914953A1 (en) 1999-04-01 2000-10-05 Basf Ag Radical-initiated emulsion polymerisation for production of aqueous polymer dispersions, for use e.g. as adhesives, carried out in presence of special metal-organic compound which is more soluble in water than in styrene
DE19917675A1 (en) * 1999-04-19 2000-10-26 Basf Ag Preparation of rubber-elastic vinyl aromatic polymer-diene block copolymer, for use in shaped articles, films or foams, involves polymerization of monomers by radical polymerization initiation
US6355756B1 (en) 1999-05-18 2002-03-12 International Business Machines Corporation Dual purpose electroactive copolymers, preparation thereof, and use in opto-electronic devices
US6197883B1 (en) 1999-06-03 2001-03-06 Ppg Industries Ohio, Inc. Thermosetting coating compositions containing flow modifiers prepared by controlled radical polymerization
US6288173B1 (en) 1999-06-03 2001-09-11 Ppg Industries Ohio, Inc. Block copolymers
US7049373B2 (en) * 1999-08-06 2006-05-23 Carnegie Mellon University Process for preparation of graft polymers
EP1222219A1 (en) * 1999-09-21 2002-07-17 Northwestern University Self-assembling compounds and use of the same to induce order in organic media
US6310175B1 (en) * 1999-10-23 2001-10-30 Nippon Shokubai Co., Ltd. Star-shaped block copolymer and production process therefor
JP2001200026A (en) * 1999-11-12 2001-07-24 Kanegafuchi Chem Ind Co Ltd Method for manufacturing block copolymer and block copolymer obtained by the same
US6403745B1 (en) * 1999-11-30 2002-06-11 Rohmax Additives Gmbh Gradient copolymers, as well as a method for their preparation and their use
US6391996B1 (en) * 1999-11-30 2002-05-21 Rohmax Additives Gmbh Copolymers obtainable by the ATRP method and a method for their preparation and their use
US6403746B1 (en) 1999-11-30 2002-06-11 Rohmax Additives Gmbh Method for preparation of a composition that contains polymer ester compounds with long-chain alkyl residues and use of this composition
US6462125B1 (en) 1999-12-16 2002-10-08 Ppg Industries Ohio, Inc. Pigment dispersions containing dispersants prepared by controlled radical polymerization having hydrophilic and hydrophobic segments
US6294014B1 (en) 1999-12-16 2001-09-25 Ppg Industries Ohio, Inc. Pigment dispersions containing dispersants prepared by controlled radical polymerization and having pendent hydrophilic polymeric segments
US6376597B1 (en) 1999-12-16 2002-04-23 Ppg Industries Ohio, Inc. Pigment dispersions containing dispersants having pendent hydrophilic polymeric segments prepared by controlled radical polymerization
US6336966B1 (en) 1999-12-16 2002-01-08 Ppg Industries Ohio, Inc. Pigment dispersions containing dispersants having core and arm star architecture prepared by controlled radical polymerization
US6306209B1 (en) 1999-12-16 2001-10-23 Ppg Industries Ohio, Inc. Pigment dispersions containing dispersants having pendent hydrophobic polymeric segments prepared by controlled radical polymerization
US6326420B1 (en) 1999-12-16 2001-12-04 Ppg Industries Ohio, Inc. Pigment dispersions containing dispersants prepared by controlled radical polymerization
US6590049B1 (en) 1999-12-16 2003-07-08 Ppg Industries Ohio, Inc. Multi-functional initiators for atom transfer radical (Co)polymerization
US6441066B1 (en) 1999-12-16 2002-08-27 Ppg Industries Ohio, Inc. Pigment dispersions containing dispersants prepared by controlled radical polymerization and having pendent hydrophobic polymeric segments
JP4607275B2 (en) * 2000-02-24 2011-01-05 日東電工株式会社 Adhesive composition, its adhesive sheet and method for producing them
JP4607274B2 (en) * 2000-02-24 2011-01-05 日東電工株式会社 Adhesive composition, its adhesive sheet and method for producing them
JP4977286B2 (en) * 2000-03-07 2012-07-18 日東電工株式会社 Method for producing polymer
US6503975B1 (en) * 2000-03-29 2003-01-07 E. I Du Pont De Nemours And Company Surfactant free aqueous emulsions
US7141646B2 (en) 2000-05-12 2006-11-28 Kaneka Corporation Method of purifying vinyl polymer
DE10027153A1 (en) * 2000-05-31 2001-12-06 Bayer Ag Block polymer, useful for optical elements and data storage contains a block comprising at least 3 repeating units not containing photoisomerizable groups and a block containing STQP groups
US6815010B2 (en) * 2000-05-31 2004-11-09 Rohm and Naas Company Method of inhibiting the loss of solar reflectance over time of an exterior elastomeric
JP4768103B2 (en) * 2000-06-06 2011-09-07 日東電工株式会社 Adhesive composition, its adhesive sheet and method for producing them
US6500871B1 (en) 2000-06-08 2002-12-31 Rhodia Chimie Process for preparing colloids of particles coming from the hydrolysis of a salt of a metal cation
GB0014225D0 (en) 2000-06-09 2000-08-02 Univ Warwick Polymerisation initiator and use
DE10036803A1 (en) * 2000-07-28 2002-02-07 Tesa Ag PSAs based on block copolymers with the structure P (A / C) -P (B) -P (A / C)
DE10036802A1 (en) * 2000-07-28 2002-02-07 Tesa Ag PSAs based on block copolymers with the structure P (A) -P (B) -P (A)
US6479425B1 (en) 2000-08-18 2002-11-12 Exxonmobile Research And Engineering Company Late transition metal complexes, their use as catalysts and polymers therefrom
US6506859B1 (en) 2000-08-18 2003-01-14 Exxonmobil Research And Engineering Company Polymerization using late transition metal catalyst complexes formed in situ
US6794461B2 (en) 2000-08-25 2004-09-21 Kaneka Corporation Method for purification of vinyl polymers
JP4679703B2 (en) * 2000-09-05 2011-04-27 ダイセル化学工業株式会社 Composite polymerization initiator
JP5005155B2 (en) 2000-10-06 2012-08-22 カーネギー−メロン ユニバーシティ Polymerization method of ionic monomer
WO2002028912A2 (en) 2000-10-06 2002-04-11 Carnegie Mellon University Preparation of nanocomposite structures by controlled polymerization
US7332550B2 (en) * 2000-10-06 2008-02-19 Carnegie Mellon University Stabilization of transition metal complexes for catalysis in diverse environments
EP1325046B1 (en) * 2000-10-06 2007-06-27 Biocompatibles UK Limited Zwitterionic polymers
WO2002028914A2 (en) * 2000-10-06 2002-04-11 Carnegie Mellon University A catalyst system for controlled polymerization
US6610801B1 (en) 2000-11-13 2003-08-26 Rohmax Additives Gmbh Processes for synthesis of polymer compositions
US6639029B1 (en) 2000-11-13 2003-10-28 Rohmax Additives Gmbh Process for continuous synthesis of polymer compositions as well as use of same
JP4768115B2 (en) * 2000-12-01 2011-09-07 日東電工株式会社 Ultraviolet crosslinking adhesive composition and method for producing the same, and adhesive sheet and method for producing the same
US6576722B2 (en) * 2000-12-13 2003-06-10 Ppg Industries Ohio, Inc. Acrylic-halogenated polyolefin copolymer adhesion promoters
US6716918B2 (en) 2000-12-22 2004-04-06 Mitsubishi Chemical Corporation Methacrylate-based polymer and process for producing the same
US6437044B1 (en) * 2001-01-26 2002-08-20 University Of Pennsylvania Living radical graft copolymerization of vinyl monomers initiated from the structural defects of polyvinylchloride
US6579947B2 (en) 2001-02-20 2003-06-17 Rhodia Chimie Hydraulic fracturing fluid comprising a block copolymer containing at least one water-soluble block and one hydrophobic block
DE10109067A1 (en) 2001-02-24 2002-09-12 Tesa Ag PSA with low outgassing behavior
US7345127B2 (en) * 2001-03-23 2008-03-18 University Of Pennsylvania Living radical polymerization of halogen-containing and acrylic monomers and the formation of block copolymers therefrom
US6911515B2 (en) 2001-03-23 2005-06-28 University Of Pennsylvania Aqueous room temperature living radical polymerization of vinyl halides
US6838535B2 (en) * 2001-03-23 2005-01-04 University Of Pennsylvania Process for the living radical polymerization of chlorine containing monomers
AU2002307151A1 (en) * 2001-04-06 2002-10-21 Carnegie Mellon University A process for the preparation of nanostructured materials
US6875832B2 (en) * 2001-04-24 2005-04-05 Ppg Industries Ohio, Inc. Synthesis of vinyl polymers by controlled radical polymerization
WO2002093246A1 (en) * 2001-05-15 2002-11-21 E Ink Corporation Electrophoretic particles
US6689844B2 (en) * 2001-05-29 2004-02-10 Rohmax Additives Gmbh Process for synthesis of polymer compositions with reduced halogen content, polymer composition with reduced halogen content as well as use of this composition
FR2829494B1 (en) 2001-07-13 2005-10-28 Rhodia Chimie Sa AQUEOUS COMPOSITIONS COMPRISING A CHEMICAL MICRO-GEL ASSOCIATED WITH A POLYMER FOR PONDING, PREPARATION AND USE
JP2003342132A (en) * 2002-05-28 2003-12-03 Mitsubishi Chemicals Corp Polymer composition for hair cosmetic and hair cosmetic using the same
JP2003342133A (en) * 2002-05-30 2003-12-03 Mitsubishi Chemicals Corp Polymer composition for hair cosmetic and hair cosmetic using the same
JP2004051549A (en) * 2002-07-19 2004-02-19 Mitsubishi Chemicals Corp Polymer composition for hair cosmetic and hair cosmetic using the same
JP2004051569A (en) * 2002-07-22 2004-02-19 Mitsubishi Chemicals Corp Polymer composition for hair cosmetic and hair cosmetic using the same
JP4039829B2 (en) * 2001-09-13 2008-01-30 三菱化学株式会社 Resin composition for cosmetics and cosmetics using the same
JP2003286142A (en) * 2002-03-29 2003-10-07 Mitsubishi Chemicals Corp Polymer composition for hair cosmetic and the resulting hair cosmetic
JP2003335637A (en) * 2002-05-21 2003-11-25 Mitsubishi Chemicals Corp Polymer composition for hair cosmetic and hair cosmetic using the same
JP4806501B2 (en) * 2001-09-25 2011-11-02 日東電工株式会社 Non-crosslinked adhesive composition, method for producing the same, and adhesive sheet
US6586530B1 (en) 2001-09-27 2003-07-01 Ppg Industries Ohio, Inc. Low surface tension (meth) acrylate containing block copolymer prepared by controlled radical polymerization
US6583223B2 (en) 2001-09-27 2003-06-24 Ppg Industries Ohio, Inc. Coating compositions which contain a low surface tension (meth) acrylate containing block copolymer flow control agent
US6841641B2 (en) 2001-09-27 2005-01-11 Ppg Industries Ohio, Inc. Copolymers comprising low surface tension (meth) acrylates
WO2003031481A2 (en) * 2001-10-12 2003-04-17 Carnegie Mellon University Simultaneous reverse and normal initiation of atrp
US7064166B2 (en) * 2001-10-12 2006-06-20 Carnegie Mellon University Process for monomer sequence control in polymerizations
US20030144441A1 (en) * 2001-11-13 2003-07-31 Ayusman Sen Controlled copolymerization of methyl acrylate with olefins under mild conditions
FR2832719B1 (en) * 2001-11-29 2004-02-13 Oreal ADHESIVE SEQUENCE ETHYLENIC COPOLYMERS, COSMETIC COMPOSITIONS CONTAINING THEM, AND USE OF SUCH COPOLYMERS IN COSMETICS
TW200407363A (en) 2001-11-29 2004-05-16 Ciba Sc Holding Ag Pigment compositions with modified ATRP copolymer dispersants
GB0131112D0 (en) * 2001-12-31 2002-02-13 Univ London Pharmacy Block copolymers
US20030225623A1 (en) * 2002-01-04 2003-12-04 John Wankmueller Method and system for conducting transactions using a payment card with account information encoded in bar code
US20030153708A1 (en) * 2002-01-11 2003-08-14 Caneba Gerald Tablada Free radical retrograde precipitation copolymers and process for making same
EP1465933B1 (en) 2002-01-16 2007-08-29 Biocompatibles UK Limited Polymer conjugates
KR100551524B1 (en) * 2002-01-22 2006-02-13 아르끄마 Method of producing and using materials which are reinforced against impact and which contain block copolymers that are obtained by means of controlled radical polymerisation in the presence of nitroxides
EP1329455A1 (en) * 2002-01-22 2003-07-23 Universiteit Gent Metal carbene complexes, methods and intermediates for making them and their use in metathesis reactions
CA2473029A1 (en) * 2002-01-22 2003-07-31 Universiteit Gent Ruthenium and osmium carbene complexes for use in metathesis
US20030158078A1 (en) 2002-02-11 2003-08-21 Jeanne Chang Detergent composition comprising a block copolymer
US20040143079A1 (en) * 2003-01-21 2004-07-22 Simion Coca Compositions containing copolymers of isobutylene type monomers
US7619040B2 (en) * 2002-02-15 2009-11-17 Ppg Industries Ohio, Inc. Compositions containing copolymers of olefinic monomers
US6784248B2 (en) * 2002-02-15 2004-08-31 Ppg Industries Ohio, Inc. Thermosetting compositions containing alternating copolymers of isobutylene type monomers
US20030216528A1 (en) * 2002-03-13 2003-11-20 Krzysztof Matyjaszewski Novel (co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
WO2003085065A2 (en) 2002-03-29 2003-10-16 Nitto Denko Corporation Polymer, producing method thereof, and photorefractive composition
US6930151B2 (en) * 2002-04-04 2005-08-16 University Of Akron Star block copolymers comprising polyisobutylene-B-polyacrylonitrile arms radiating from an aromatic core
DE10227338B4 (en) 2002-06-19 2006-05-24 Byk-Chemie Gmbh Use of polyacrylate-modified polysiloxanes as flow control agents in coating compositions
SE0202016D0 (en) * 2002-06-27 2002-06-27 Amersham Biosciences Ab Polymeric Support Having Novel Pore Structures
JP3606855B2 (en) * 2002-06-28 2005-01-05 ドン ウン インターナショナル カンパニー リミテッド Method for producing carbon nanoparticles
DE10234246A1 (en) * 2002-07-27 2004-02-05 Tesa Ag Pressure-sensitive adhesive material for bonding transparent substrates, e.g. in liquid crystal displays and other optical applications, comprises block copolymers with blocks of different refractive index
JP2004059783A (en) * 2002-07-30 2004-02-26 Kanegafuchi Chem Ind Co Ltd Curable composition having mold releasability
JP4493498B2 (en) * 2002-08-02 2010-06-30 株式会社カネカ Acrylic block copolymer and thermoplastic resin composition
DE10235696B4 (en) * 2002-08-03 2005-09-15 Degussa Construction Chemicals Gmbh Process for the preparation of homo-, co- and block polymers
FR2843314B1 (en) 2002-08-06 2004-09-24 Rhodia Chimie Sa SYNTHESIS OF STATISTICAL MICROGELS BY CONTROLLED RADICAL POLYMERIZATION
FR2843394B1 (en) * 2002-08-07 2005-12-30 Atofina ALCOXYAMINES FROM NITROXIDES B-PHOSPHORUS, THEIR USE IN RADICAL POLYMERIZATION
DE10236133A1 (en) * 2002-08-07 2004-02-26 Byk-Chemie Gmbh Use of gradient copolymers produced by living, controlled polymerization of ethylenically unsaturated monomers as dispersants, especially in coating compositions, pastes or molding materials
EP1534764B1 (en) * 2002-08-09 2014-07-16 Carnegie Mellon University Polymers, supersoft elastomers and methods for preparing the same
DE10237286A1 (en) * 2002-08-14 2004-02-26 Degussa Construction Chemicals Gmbh Use of block copolymers produced by polymerizing a polyalkylene oxide compound with an ethylenically unsaturated monomer as dispersants for aqueous suspensions, e.g. cement mixes
US6841636B2 (en) * 2002-08-19 2005-01-11 National Starch And Chemical Investment Holding Corporation Dispersions containing living radicals
US7375175B2 (en) * 2002-08-19 2008-05-20 National Starch And Chemical Investment Holding Corporation Dispersions containing living radicals
FR2846973B1 (en) 2002-11-07 2004-12-17 Rhodia Chimie Sa ANTI-WRINKLE COMPOSITION COMPRISING A COPOLYMER WITH CONTROLLED ARCHITECTURE FOR TEXTILE FIBER ARTICLES
US6806320B2 (en) * 2002-11-15 2004-10-19 3M Innovative Properties Company Block copolymer melt-processable compositions, methods of their preparation, and articles therefrom
US6992217B2 (en) * 2002-12-11 2006-01-31 3M Innovative Properties Company Ring-opened azlactone initiators for atom transfer radical polymerization
US6894133B2 (en) * 2002-12-11 2005-05-17 3M Innovative Properties Company Azlactone initiators for atom transfer radical polymerization
EP1433799A3 (en) * 2002-12-23 2004-07-14 Ucb, S.A. Star shaped acrylic block copolymer
US9348226B2 (en) * 2002-12-28 2016-05-24 Jsr Corporation Radiation-sensitive resin composition
TWI237032B (en) * 2002-12-31 2005-08-01 Ind Tech Res Inst Polyacrylonitrile block copolymer and method for producing the same
GB0301014D0 (en) 2003-01-16 2003-02-19 Biocompatibles Ltd Conjugation reactions
US6677413B1 (en) * 2003-02-05 2004-01-13 3M Innovative Properties Company Azlactone initiators for nitroxide-mediated polymerization
US6680362B1 (en) 2003-02-05 2004-01-20 3M Innovative Properties Company Ring-opened azlactone initiators for nitroxide-mediated polymerization
TWI344578B (en) * 2003-02-20 2011-07-01 Promerus Llc Dissolution rate modifiers for photoresist compositions
US7754839B2 (en) * 2003-03-03 2010-07-13 The Regents Of The University Of California Quasi-living metal catalyst for ethylene homo-polymerization and co-polymerization with 5-norbornen -2-yl acetate
US6908952B2 (en) * 2003-03-21 2005-06-21 3M Innovative Properties Company Ring-opened azlactone photoiniferters for radical polymerization
US6747104B1 (en) 2003-03-21 2004-06-08 3M Innovative Properties Company Azlactone photoiniferters for radical polymerization
US6762257B1 (en) * 2003-05-05 2004-07-13 3M Innovative Properties Company Azlactone chain transfer agents for radical polymerization
US6753391B1 (en) * 2003-05-05 2004-06-22 3M Innovative Properties Company Ring-opened azlactone chain transfer agents for radical polymerization
GB0314472D0 (en) * 2003-06-20 2003-07-23 Warwick Effect Polymers Ltd Polymer
EP1642932B1 (en) 2003-07-08 2012-03-21 Kaneka Corporation Curing composition
FR2859728B1 (en) * 2003-09-15 2008-07-11 Oreal ETHYLENIC COPOLYMER SEQUENCES COMPRISING A VINYLLACTAM SEQUENCE, COSMETIC OR PHARMACEUTICAL COMPOSITIONS CONTAINING THEM, AND THE USE OF THESE COPOLYMERS IN COSMETICS
US20050238594A1 (en) * 2003-09-15 2005-10-27 Nathalie Mougin Block ethylenic copolymers comprising a vinyllactam block, cosmetic or pharmaceutical compositions comprising them and cosmetic use of these copolymers
JP2005139251A (en) * 2003-11-05 2005-06-02 Canon Inc Block copolymer, polymer-containing composition containing the same, ink composition, ink-application method and apparatus
KR20070119097A (en) * 2003-11-26 2007-12-18 닛뽕소다 가부시키가이샤 Novel multi-branched polymer
US7468413B2 (en) 2004-01-30 2008-12-23 Khodia Inc. Rare earth aggregate formulation using di-block copolmers
US20060057180A1 (en) * 2004-02-20 2006-03-16 Ashutosh Chilkoti Tunable nonfouling surface of oligoethylene glycol
US20070185343A1 (en) * 2004-02-26 2007-08-09 Universiteit Gent Metal complexes for use in olefin metathesis and atom group transfer reactions
US7342077B2 (en) 2004-06-04 2008-03-11 Basf Corporation Acrylic composition and a method of forming the same via free-radical polymerization
US7220811B2 (en) * 2004-03-04 2007-05-22 Basf Corporation Acrylic composition and a curable coating composition including the same
US7250480B2 (en) * 2004-03-04 2007-07-31 Basf Corporation Acrylic composition and a curable coating composition including the same
US7375174B2 (en) * 2004-03-04 2008-05-20 Basf Corporation Acrylic composition and a curable coating composition including the same
US7893174B2 (en) * 2004-03-05 2011-02-22 Carnegie Mellon University Atom transfer radical polymerization process
US7795355B2 (en) * 2004-03-05 2010-09-14 Carnegie Mellon University Preparation of functional polymers
US7632905B2 (en) 2004-04-09 2009-12-15 L'oreal S.A. Block copolymer, composition comprising it and cosmetic treatment process
EP1739133A4 (en) 2004-04-05 2009-08-12 Kaneka Corp Curable compositions
US7250121B2 (en) * 2004-05-13 2007-07-31 Nitto Denko Corporation Non-linear optical device material composition
US20050253120A1 (en) * 2004-05-13 2005-11-17 Michiharu Yamamoto Non-linear optical device material composition
DE602005014972D1 (en) * 2004-05-26 2009-07-30 Dentsply Detrey Gmbh PARTICLE
FR2871470B1 (en) 2004-06-11 2007-01-12 Oreal GRADIENT COPOLYMER, COMPOSITION AND COSMETIC PROCESS FOR MAKE-UP OR CARE
FR2872039B1 (en) * 2004-06-23 2006-08-04 Rhodia Chimie Sa COSMETIC COMPOSITION COMPRISING POLYORGANOSILOXANE AND USES THEREOF
JP2006016488A (en) * 2004-07-01 2006-01-19 Toyo Ink Mfg Co Ltd Organic pigment-grafted with resin and method for producing the same
JP2008504411A (en) * 2004-07-01 2008-02-14 ウニベルズィタイト・ヘント Monodisperse polymer containing (alkyl) acrylic acid moiety, precursor, method for producing the same, and application thereof
US8563213B2 (en) 2004-07-16 2013-10-22 Transitions Optical, Inc. Methods for producing photosensitive microparticles
US20060079624A1 (en) * 2004-10-08 2006-04-13 Hildeberto Nava Crosslinkable polymer systems
JP5090915B2 (en) * 2004-10-08 2012-12-05 フイルメニツヒ ソシエテ アノニム Amphiphilic star block polymer
US7317058B2 (en) * 2004-11-01 2008-01-08 Nitto Denko Corporation (Meth)acrylate polymer and non-linear optical device material composition
US7279446B2 (en) 2004-11-15 2007-10-09 Rhodia Inc. Viscoelastic surfactant fluids having enhanced shear recovery, rheology and stability performance
WO2006074969A1 (en) 2005-01-11 2006-07-20 Ciba Specialty Chemicals Holding Inc. Process for the post-modification of homo and copolymers prepared by controlled free radical polymerization processes
US20060173142A1 (en) * 2005-02-01 2006-08-03 Hildeberto Nava Functionalized thermosetting resin systems
JP2008530326A (en) * 2005-02-04 2008-08-07 アグフア・グラフイクス・ナームローゼ・フエンノートシヤツプ Pigment dispersion comprising a copolymer comprising an ionic aromatic monomer
JP4768997B2 (en) * 2005-02-24 2011-09-07 株式会社リコー Compound
CN101128491B (en) * 2005-02-25 2010-09-08 三井化学株式会社 Polymerization catalyst composition and process for production of polymer
JP4742647B2 (en) * 2005-03-31 2011-08-10 住友化学株式会社 Method for producing polar monomer-olefin copolymer
JP2008536699A (en) * 2005-04-14 2008-09-11 プレジデント・アンド・フエローズ・オブ・ハーバード・カレツジ Tunable solubility in sacrificial layers for microfabrication
US7279527B2 (en) * 2005-04-22 2007-10-09 Bridgestone Corporation Method of converting anionic living end to protected free radical living end and applications thereof
WO2006138213A1 (en) * 2005-06-13 2006-12-28 Alcon, Inc. Ophthalmic and otorhinolaryngological device materials
KR101308951B1 (en) * 2005-06-13 2013-09-24 알콘, 인코퍼레이티드 Ophthalmic and otorhinolaryngological device materials
US8263721B2 (en) * 2005-06-13 2012-09-11 Novartis Ag Ophthalmic and otorhinolaryngological device materials
EP1754731A1 (en) 2005-08-16 2007-02-21 Nederlandse Organisatie voor Toegepast-Natuuurwetenschappelijk Onderzoek TNO Method of modifying materials surfaces
GB0517137D0 (en) 2005-08-22 2005-09-28 Viacatt N V Multicoordinated metal complexes for use in metalthesis reactions
WO2007025086A2 (en) 2005-08-23 2007-03-01 Carnegie Mellon University Atom transfer radical polymerization in microemulsion and true emulsion polymerization
US20080319131A1 (en) * 2005-08-26 2008-12-25 Mccullough Richard D Electrically Conductive Polymers and Raft Polymerization
WO2007025310A1 (en) * 2005-08-26 2007-03-01 Carnegie Mellon University Polymerization process with catalyst reactivation
DE102005041528A1 (en) 2005-08-31 2007-03-01 Rohmax Additives Gmbh Multi-arm star-shaped polymer for use as lubricating oil additive, e.g. viscosity modifier or dispersant, has at least three arms containing units derived from esters of higher alkanols and unsaturated carboxylic acids
WO2007029733A1 (en) 2005-09-08 2007-03-15 Kaneka Corporation Curable composition
US20070123646A1 (en) * 2005-09-13 2007-05-31 Lele Bhalchandra S Protein-polymer conjugates and synthesis thereof
ATE546160T1 (en) 2005-09-14 2012-03-15 Ucb Pharma Sa ANTIBODY COMB POLYMER CONJUGATE
US7713689B2 (en) * 2005-09-15 2010-05-11 Duke University Non-fouling polymeric surface modification and signal amplification method for biomolecular detection
JP5243797B2 (en) 2005-09-22 2013-07-24 株式会社カネカ Photo radical curing / photo cationic curing combined curable composition
ES2336473T5 (en) * 2005-09-26 2014-01-07 Nippon Shokubai Co., Ltd. Polymer, process for its preparation and cement mixture containing it
DE602006021228D1 (en) 2005-12-13 2011-05-19 Kaneka Corp HARDENABLE COMPOSITION FOR DAMPING MATERIAL AND DAMPING MATERIAL
WO2007075817A1 (en) * 2005-12-21 2007-07-05 Carnegie Mellon University Preparation of block copolymers
US7671152B2 (en) * 2005-12-22 2010-03-02 The Goodyear Tire & Rubber Company Surfactantless synthesis of amphiphilic cationic block copolymers
WO2007074890A1 (en) 2005-12-28 2007-07-05 Kaneka Corporation Curable composition in combination with thermal radical curing/thermal latent curable epoxy
EP2586804B1 (en) 2005-12-28 2014-04-02 Kaneka Corporation Photoradically and thermally radically curable composition
US8389630B2 (en) 2005-12-28 2013-03-05 Kaneka Corporation Curable composition
US20100222449A1 (en) 2006-01-18 2010-09-02 Kaneka Corporation Curable composition
EP1992646A4 (en) 2006-02-14 2010-02-24 Kaneka Corp Vinyl polymer having polar functional group and method for production thereof
EP3222142A1 (en) 2006-02-28 2017-09-27 Kodiak Sciences Inc. Acryloyloxyethylphosphorylcholine containing polymer conjugates and their preparation
KR20090005089A (en) 2006-03-29 2009-01-12 미쓰이 가가쿠 가부시키가이샤 Resin composition containing olefin block polymer and use of the same
US7728092B1 (en) 2006-04-13 2010-06-01 Henkel Corporation Anaerobically curable compositions
WO2007139463A1 (en) * 2006-05-29 2007-12-06 Ge Healthcare Bio-Sciences Ab Preparation of monolithic articles
US20080153077A1 (en) * 2006-06-12 2008-06-26 David Henry Substrates for immobilizing cells and tissues and methods of use thereof
EP1873205A1 (en) * 2006-06-12 2008-01-02 Corning Incorporated Thermo-responsive blends and uses thereof
JP5421773B2 (en) * 2006-07-25 2014-02-19 日東電工株式会社 Nonlinear optical device sensitive to green laser
US7736548B2 (en) * 2006-07-25 2010-06-15 Nitto Denko Corporation Non-linear optical device with long grating persistency
JP5597325B2 (en) * 2006-08-04 2014-10-01 ザ トラスティーズ オブ ザ ユニバーシティ オブ ペンシルバニア Living radical polymerization of activated and deactivated monomers containing electron withdrawing side groups.
US8349410B2 (en) 2006-08-17 2013-01-08 University of Pittsburgh—of the Commonwealth System of Higher Education Modification of surfaces with polymers
WO2008020614A1 (en) 2006-08-18 2008-02-21 Kaneka Corporation Method for producing branched vinyl polymer having functional group
EP2455453A1 (en) * 2006-09-06 2012-05-23 Corning Incorporated Substrate for immobilizing cells or tissue
WO2008041768A1 (en) 2006-10-05 2008-04-10 Kaneka Corporation Curable composition
US8367051B2 (en) * 2006-10-09 2013-02-05 Carnegie Mellon University Preparation of functional gel particles with a dual crosslink network
FR2909093B1 (en) * 2006-11-28 2012-07-13 Arkema France 3D OPTICAL MEMORY COMPRISING A BLOCK COPOLYMER CONTAINING A PHOTOACTIVE MONOMER CARRYING A PHOTOISOMERIZABLE GROUP.
FR2909094A1 (en) * 2006-11-28 2008-05-30 Arkema France 3D OPTICAL MEMORY COMPRISING MULTILAYER PARTICLES COMPRISING A PHOTOACTIVE MONOMER WITH A PHOTOISOMERIZABLE GROUP.
US7994101B2 (en) * 2006-12-12 2011-08-09 Halliburton Energy Services, Inc. Corrosion inhibitor intensifier compositions and associated methods
US8030410B2 (en) 2006-12-29 2011-10-04 Bridgestone Corporation Method for generating free radical capable polymers using carbonyl-containing compounds
US7560509B2 (en) * 2006-12-29 2009-07-14 Bridgestone Corporation Method of directing grafting by controlling the location of high vinyl segments in a polymer
US7737218B2 (en) 2006-12-29 2010-06-15 Bridgestone Corporation Method for generating free radical capable polymers using tin or silicon halide compounds
US7396887B1 (en) * 2006-12-29 2008-07-08 Bridgestone Corporation Insitu removal of chelator from anionic polymerization reactions
US20080157641A1 (en) * 2006-12-31 2008-07-03 Rachael Wren Grout Multi-use Free Standing Seating and Storage Unit
FR2911609B1 (en) * 2007-01-19 2009-03-06 Rhodia Recherches & Tech DIBLOC COPOLYMER COMPRISING STYRENE-DERIVING UNITS AND ACRYLIC ACID-DERIVING UNITS
FR2923487B1 (en) * 2007-11-09 2009-12-04 Rhodia Operations AMPHOLYTE COPOLYMER WITH CONTROLLED ARCHITECTURE
DE102007006105A1 (en) 2007-02-02 2008-08-07 Evonik Röhm Gmbh Process for the preparation of telechelic polymers
US9056988B2 (en) 2007-02-05 2015-06-16 Ppg Industries Ohio, Inc. Solar reflective coatings and coating systems
WO2008122576A1 (en) 2007-04-05 2008-10-16 Dsm Ip Assets B.V. Aqueous oligomer / polymer emulsion with cationic functionality
FI122734B (en) 2007-05-21 2012-06-15 Kemira Oyj Process chemical for use in the manufacture of paper or board
WO2009023353A1 (en) * 2007-05-23 2009-02-19 Carnegie Mellon University Hybrid particle composite structures with reduced scattering
US8252880B2 (en) * 2007-05-23 2012-08-28 Carnegie Mellon University Atom transfer dispersion polymerization
WO2008154331A1 (en) * 2007-06-07 2008-12-18 Chevron U.S.A. Inc. Removal of branched dibenzothiophenes from hydrocarbon mixtures via charge transfer complexes with a tapa-functionalized adsorbent
DE102007046223A1 (en) 2007-09-26 2009-04-02 Evonik Rohmax Additives Gmbh Use of comb polymer comprising repeating units derived from polyolefin-based macro-monomer and repeating units derived from low molecular monomers comprising e.g. styrene monomer, to reduce fuel consumption in motor vehicles
DE102007032120A1 (en) 2007-07-09 2009-01-15 Evonik Rohmax Additives Gmbh Use of comb polymer comprising polyolefin-based macro-monomer derived from repeating units and repeating units derived from low molecular monomers comprising e.g. styrene monomer, to reduce the fuel consumption in motor vehicles
DE102007036856A1 (en) 2007-08-06 2009-02-26 Evonik Rohmax Additives Gmbh Use of ester-group-containing polymers as antifatigue additives
DE102007043048A1 (en) 2007-09-11 2009-03-12 Byk-Chemie Gmbh Polypropylene-containing polyethers and their mixtures with poly (meth) acrylates as powder coating development agent
US20090074709A1 (en) * 2007-09-14 2009-03-19 Koepsel Richard R Methods, devices and systems for biocidal surface activity
FR2921663A1 (en) 2007-10-02 2009-04-03 Bluestar Silicones France Soc POLYORGANOSILOXANES WITH PIPERIDINE FUNCTION WITHOUT CUTANE CONTACT TOXICITY AND USE OF THE SAME IN COSMETIC COMPOSITIONS
TWI426931B (en) * 2007-10-03 2014-02-21 Alcon Inc Ophthalmic and otorhinolaryngological device materials
TWI461186B (en) * 2007-10-05 2014-11-21 Alcon Inc Ophthalmic and otorhinolaryngological device materials
TWI426932B (en) 2007-10-05 2014-02-21 Alcon Inc Ophthalmic and otorhinolaryngological device materials
US20090111957A1 (en) * 2007-10-31 2009-04-30 National Taipei University Of Technology Fluoro-ponytailed bipyridine derivatives and their use as ligands in the metal-catalyzed atrp
US7789160B2 (en) * 2007-10-31 2010-09-07 Rhodia Inc. Addition of nonionic surfactants to water soluble block copolymers to increase the stability of the copolymer in aqueous solutions containing salt and/or surfactants
EP2205826A4 (en) * 2007-10-31 2011-06-29 Rhodia Addition of zwitterionic surfactant to water soluble polymer to increase the stability of the polymers in aqueous solutions containing salt and/or surfactants
US8058211B2 (en) * 2007-12-12 2011-11-15 Halliburton Energy Services, Inc. Corrosion inhibitor intensifier compositions and associated methods
US20090156771A1 (en) * 2007-12-17 2009-06-18 Youqing Shen Amine-Containing Compounds for Enhancing the Activity of ATRP Catalysts and Removal of the Terminal Halogen Groups from the ATRP Polymer Products
BRPI0821204A2 (en) * 2007-12-18 2017-05-09 Basf Se biodiesel fuel composition, and method for improving the cold flow properties of a biodiesel fuel composition
US20090171049A1 (en) * 2007-12-27 2009-07-02 Linhardt Jeffrey G Segmented reactive block copolymers
WO2009085754A1 (en) * 2007-12-27 2009-07-09 Bausch & Lomb Incorporated Segmented interactive block copolymers
WO2009085759A1 (en) * 2007-12-27 2009-07-09 Bausch & Lomb Incorporated Segmented reactive block copolymers
US8796184B2 (en) 2008-03-28 2014-08-05 Sentilus, Inc. Detection assay devices and methods of making and using the same
CN101784568B (en) 2008-05-07 2014-03-26 高级软质材料株式会社 Polyrotaxane, crosslinked structure comprising polyrotaxane and polymer, and processes for producing these
FR2931827A1 (en) * 2008-05-27 2009-12-04 Arkema France BLOCK COPOLYMER CONTAINING A PHOTOACTIVE MONOMER WITH A PHOTOISOMERIZABLE GROUP, USE THEREOF IN A 3D OPTICAL MEMORY.
US8829136B2 (en) * 2008-06-18 2014-09-09 Henkel US IP LLC Apparatus and methods for controlled radical polymerization
EP2291412B1 (en) * 2008-06-18 2013-07-24 Henkel Corporation Apparatus and methods for controlled radical polymerization
US8664324B2 (en) 2008-06-23 2014-03-04 Basf Se Pigment dispersants with modified copolymers
FR2934154B1 (en) * 2008-07-23 2010-08-13 Rhodia Operations THERMOSENSITIVE EMULSIONS
EP2313184B1 (en) * 2008-08-05 2012-10-10 Polymers CRC Limited Functionalized thin film polyamide membranes
EP2160945A1 (en) 2008-09-09 2010-03-10 Polymers CRC Limited Antimicrobial Article
EP2160946A1 (en) 2008-09-09 2010-03-10 Polymers CRC Limited Process for the preparation of an antimicrobial article
US20100099789A1 (en) * 2008-10-20 2010-04-22 Nitto Denko Corporation Method for modulating light of photorefractive composition
US20100096603A1 (en) * 2008-10-20 2010-04-22 Nitto Denko Corporation Optical devices responsive to near infrared laser and methods of modulating light
FR2937336B1 (en) 2008-10-22 2011-06-10 Rhodia Operations COMPOSITION FOR HOUSEHOLD CARE COMPRISING A CATIONIC NANOGEL
US8822610B2 (en) * 2008-12-22 2014-09-02 ATRP Solutions, Inc. Control over controlled radical polymerization processes
US8815971B2 (en) 2008-12-22 2014-08-26 ATRP Solutions, Inc. Control over controlled radical polymerization processes
US20100162693A1 (en) 2008-12-31 2010-07-01 Michael Paul W Method of reducing torque ripple in hydraulic motors
EP2376609A1 (en) 2009-01-13 2011-10-19 Evonik RohMax Additives GmbH Fuel compositions having improved cloud point and improved storage properties
FR2941704B1 (en) 2009-01-30 2011-12-23 Arkema France BLOCK COPOLYMERS WITH ASSOCIATIVE GROUPS AND ADHESIVE COMPRISING SAME
US8110797B2 (en) 2009-02-06 2012-02-07 Florida State University Research Foundation, Inc. Electrospray ionization mass spectrometry methodology
DE102009001446A1 (en) 2009-03-10 2010-09-23 Evonik Rohmax Additives Gmbh Use of comb polymers as antifatigue additives
DE102009001447A1 (en) 2009-03-10 2010-09-16 Evonik Rohmax Additives Gmbh Use of comb polymers to improve the load carrying capacity
GB2481561B (en) 2009-03-27 2013-12-11 Univ Carnegie Mellon Preparation of functional star macromolecules
US9783628B2 (en) 2009-04-23 2017-10-10 ATRP Solutions, Inc. Dual-mechanism thickening agents for hydraulic fracturing fluids
WO2010123575A1 (en) 2009-04-23 2010-10-28 Atrp Solutions Inc Well defined stars with segmented arms
US8173750B2 (en) 2009-04-23 2012-05-08 ATRP Solutions, Inc. Star macromolecules for personal and home care
WO2010123574A1 (en) 2009-04-23 2010-10-28 Atrp Solutions Inc Star macromolecules for personal and home care
DE102009002730A1 (en) 2009-04-29 2010-11-04 Evonik Rohmax Additives Gmbh Preparing copolymer, useful as additive for e.g. mineral oil and ester oil, comprises polymerizing a monomer composition (comprising e.g. ethylenically unsaturated ester compounds and comonomer) in the presence of alkyl(ene) compounds
US8673295B2 (en) 2009-04-30 2014-03-18 University of Pittsburgh—of the Commonwealth System of Higher Education Thermoresponsive, biodegradable, elastomeric material and uses therefor
US8470205B2 (en) * 2009-06-05 2013-06-25 Air Products And Chemicals, Inc. Electrically conductive films formed from dispersions comprising conductive polymers and hyperbranched polymers
GB0912160D0 (en) 2009-07-13 2009-08-26 Warwick Effect Polymers Ltd Polymer modified macromolecules
EP2453942B1 (en) 2009-07-15 2014-08-13 Technical University of Denmark Polymer coating comprising 2-methoxyethyl acrylate units synthesized by surface-initiated atom transfer radical polymerization
ATE547472T1 (en) 2009-09-25 2012-03-15 Evonik Rohmax Additives Gmbh COMPOSITION FOR IMPROVING THE COLD FLOW PROPERTIES OF FUEL OILS
CN101691417B (en) * 2009-10-13 2011-05-25 华东理工大学 Preparation method of star poly-(methyl)acrylate long-chain ester polymer
WO2011068596A2 (en) 2009-12-01 2011-06-09 Silberline Manufacturing Company, Inc. Polymer encapsulated aluminum particulates
WO2011075185A1 (en) 2009-12-18 2011-06-23 Oligasis Targeted drug phosphorylcholine polymer conjugates
DE102010001040A1 (en) 2010-01-20 2011-07-21 Evonik RohMax Additives GmbH, 64293 (Meth) acrylate polymers for improving the viscosity index
US20110192076A1 (en) 2010-02-05 2011-08-11 Evonik Rohmax Additives Gmbh Composition having improved filterability
CN101787093B (en) * 2010-03-12 2012-01-18 江苏工业学院 Self-initiated atom transfer radical polymerization method of Dimethylaminoethyl Methacrylate
WO2011134694A1 (en) 2010-04-26 2011-11-03 Evonik Rohmax Additives Gmbh A polymer useful as viscosity index improver
DE102010028195A1 (en) 2010-04-26 2011-10-27 Evonik Rohmax Additives Gmbh Lubricant for transmissions
EP2571421B1 (en) 2010-05-17 2017-08-02 Sentilus Holdco, LLC Detection devices and related methods of use
CN102295712B (en) * 2010-06-24 2013-02-27 中国科学院化学研究所 Water-phase ligand-free transition metal catalytic activity/controllable free radical polymerization method
US8912252B2 (en) 2010-07-20 2014-12-16 Silberline Manufacturing Company, Inc. Film-forming pigments and coating system including the same
US8815982B2 (en) 2010-07-20 2014-08-26 Silberline Manufacturing Company, Inc. Colored system
DE102010038615A1 (en) 2010-07-29 2012-02-02 Evonik Rohmax Additives Gmbh Polyalkyl (meth) acrylate for improving lubricating oil properties
WO2012020545A1 (en) 2010-08-10 2012-02-16 株式会社カネカ Manufacturing method of (meth) acrylic polymer
US8816001B2 (en) 2010-09-10 2014-08-26 Franklin And Marshall College Genetically encoded initiator for polymer growth from proteins
FR2965264B1 (en) 2010-09-27 2013-11-29 Rhodia Operations CONTROLLED RADICAL POLYMERIZATION OF N-VINYL LACTAMS IN AQUEOUS MEDIUM
FR2965564B1 (en) 2010-09-30 2012-10-26 Rhodia Operations PREPARATION OF HIGH-MASS HYDROPHILIC POLYMERS BY CONTROLLED RADICAL POLYMERIZATION
US20130253143A1 (en) 2010-09-30 2013-09-26 Kaneka Corporation Composition containing branched polymer for damping material
RU2013124369A (en) 2010-10-29 2014-12-10 Эвоник Ойл Эддитивс ГмбХ DIESEL ENGINE WITH IMPROVED PROPERTIES
US9587064B2 (en) 2010-12-08 2017-03-07 ATRP Solutions, Inc. Salt-tolerant star macromolecules
WO2012076285A1 (en) 2010-12-10 2012-06-14 Evonik Rohmax Additives Gmbh A lubricant composition
WO2012076676A1 (en) 2010-12-10 2012-06-14 Evonik Rohmax Additives Gmbh A viscosity index improver comprising a polyalkyl(meth)acrylate polymer
US9518249B2 (en) 2010-12-16 2016-12-13 General Electric Company Cell carrier, associated methods for making cell carrier and culturing cells using the same
US9534206B2 (en) 2010-12-16 2017-01-03 General Electric Company Cell carrier, associated methods for making cell carrier and culturing cells using the same
US9453196B2 (en) 2010-12-16 2016-09-27 General Electric Company Cell carrier, methods of making and use
US9926523B2 (en) 2010-12-16 2018-03-27 General Electric Company Cell carriers and methods for culturing cells
US9453197B2 (en) 2010-12-16 2016-09-27 General Electric Company Methods of making cell carrier
US9644042B2 (en) 2010-12-17 2017-05-09 Carnegie Mellon University Electrochemically mediated atom transfer radical polymerization
DE102011003855A1 (en) 2011-02-09 2012-08-09 Evonik Rohmax Additives Gmbh Process for dewaxing mineral oil compositions
BR112013021923A2 (en) 2011-03-25 2016-11-08 Evonik Oil Additives Gmbh composition to improve oxidation stability of fuel oils
DE102011075969A1 (en) 2011-05-17 2012-11-22 Evonik Rohmax Additives Gmbh Friction-improving polymers for DLC-coated surfaces
DE102011076364A1 (en) 2011-05-24 2012-11-29 Evonik Rohmax Additives Gmbh Lubricant composition with phosphate-functionalized polymers
US9057835B2 (en) 2011-06-06 2015-06-16 Ppg Industries Ohio, Inc. Coating compositions that transmit infrared radiation and exhibit color stability and related coating systems
EP2551338A1 (en) 2011-07-27 2013-01-30 Henkel AG & Co. KGaA Laundry detergent compositions with stain removal properties
WO2013028756A1 (en) 2011-08-22 2013-02-28 Carnegie Mellon University Atom transfer radical polymerization under biologically compatible conditions
JP2014525486A (en) * 2011-08-30 2014-09-29 ビーエーエスエフ ソシエタス・ヨーロピア Production of polymers by controlled radical polymerization.
US9790305B2 (en) 2011-09-09 2017-10-17 Franklin And Marshall College Site specifically incorporated initiator for growth of polymers from proteins
US9832818B2 (en) 2011-09-30 2017-11-28 Ppg Industries Ohio, Inc. Resistive heating coatings containing graphenic carbon particles
US9761903B2 (en) 2011-09-30 2017-09-12 Ppg Industries Ohio, Inc. Lithium ion battery electrodes including graphenic carbon particles
US10294375B2 (en) 2011-09-30 2019-05-21 Ppg Industries Ohio, Inc. Electrically conductive coatings containing graphenic carbon particles
US9938416B2 (en) 2011-09-30 2018-04-10 Ppg Industries Ohio, Inc. Absorptive pigments comprising graphenic carbon particles
US10763490B2 (en) 2011-09-30 2020-09-01 Ppg Industries Ohio, Inc. Methods of coating an electrically conductive substrate and related electrodepositable compositions including graphenic carbon particles
US10240052B2 (en) 2011-09-30 2019-03-26 Ppg Industries Ohio, Inc. Supercapacitor electrodes including graphenic carbon particles
US9475946B2 (en) 2011-09-30 2016-10-25 Ppg Industries Ohio, Inc. Graphenic carbon particle co-dispersions and methods of making same
US9574094B2 (en) 2013-12-09 2017-02-21 Ppg Industries Ohio, Inc. Graphenic carbon particle dispersions and methods of making same
US9988551B2 (en) 2011-09-30 2018-06-05 Ppg Industries Ohio, Inc. Black pigments comprising graphenic carbon particles
MX354132B (en) 2011-10-24 2018-02-14 Rhodia Operations Preparation of amphiphilic block polymers by controlled radical micellar polymerisation.
US9540455B2 (en) * 2011-12-22 2017-01-10 Lanxess International Sa Process for preparing cured polymers
MX350257B (en) 2012-01-18 2017-08-31 Univ Iowa State Res Found Inc Thermoplastic elastomers via atom transfer radical polymerization of plant oil.
WO2013158183A2 (en) 2012-01-27 2013-10-24 Carnegie Mellon University Processable self-organizing nanoparticles
EP2809698B1 (en) 2012-01-31 2016-01-27 Rhodia Operations Dispersed phase polymerisation of halogenated vinyl monomers in the presence of live reactive stabilisers
EP2809697B1 (en) 2012-01-31 2017-07-19 Rhodia Operations Live poly(n-vinyl lactam) reactive stabilisers for dispersed phase polymerisation
WO2013126745A2 (en) 2012-02-23 2013-08-29 Carnegie Mellon University Ligands designed to provide highly active catalyst complexes
EP2817370B1 (en) 2012-02-23 2020-08-19 Basf Se Fluorinated acrylate block copolymers with low dynamic surface tension
JP5888648B2 (en) * 2012-02-29 2016-03-22 ニッタ株式会社 Method for producing temperature-sensitive adhesive
FR2987837B1 (en) 2012-03-09 2014-03-14 Rhodia Operations RADICAL CONTROLLED POLYMERIZATION IN WATER-IN-WATER DISPERSION
WO2013138494A1 (en) 2012-03-13 2013-09-19 California Institute Of Technology Periodic nanostructures from self assembled wedge-type block-copolymers
US9382387B2 (en) 2012-03-13 2016-07-05 California Institute Of Technology Rapid self-assembly of block copolymers to photonic crystals
JP2015514853A (en) 2012-04-27 2015-05-21 エボニック オイル アディティヴス ゲゼルシャフト ミット ベシュレンクテル ハフツングＥｖｏｎｉｋ Ｏｉｌ Ａｄｄｉｔｉｖｅｓ ＧｍｂＨ Use of cold flow enhancing compositions for fuels, their blends with biofuels and their preparations
US8975346B2 (en) 2012-05-18 2015-03-10 Sabic Global Technologies B.V. Polycarbonate copolymers via controlled radical polymerization
JP6226967B2 (en) 2012-06-06 2017-11-08 ヴァンダービルト ケミカルズ、エルエルシー Lubricant with good fuel efficiency
US9453943B2 (en) 2012-06-28 2016-09-27 California Institute Of Technology Photonic structures from self assembly of brush block copolymers and polymer blends
CN105189643B (en) 2012-08-30 2019-01-15 派诺聚合物技术公司 Double mechanism thickener for hydrofrac fluid
WO2014040919A1 (en) 2012-09-13 2014-03-20 Evonik Oil Additives Gmbh A composition to improve low temperature properties and oxidation stability of vegetable oils and animal fats
AU2013330344B2 (en) 2012-09-17 2018-07-05 W. R. Grace & Co.-Conn. Chromatography media and devices
JP6469574B2 (en) 2012-09-17 2019-02-13 ダブリュー・アール・グレース・アンド・カンパニー−コーンＷ Ｒ Ｇｒａｃｅ ＆ Ｃｏ−Ｃｏｎｎ Functionalized granular carrier and its production and use
US9914870B2 (en) 2013-01-22 2018-03-13 Carnegie Mellon University Lignin-containing polymers and compositions including lignin-containing polymers
RU2656213C2 (en) 2013-02-04 2018-06-01 Эвоник Ойль Эддитифс Гмбх Cold flow improver with broad applicability in mineral diesel, biodiesel and blends thereof
CA2899349C (en) 2013-02-04 2021-09-21 ATRP Solutions, Inc. Salt-tolerant star macromolecules
US20140256874A1 (en) 2013-03-05 2014-09-11 Ppg Industries Ohio, Inc. Curable solid particulate compositions
WO2014151543A1 (en) 2013-03-15 2014-09-25 Ppg Industries Ohio, Inc. Controlled radical polymerization initiators
CN103205202A (en) * 2013-04-03 2013-07-17 中山职业技术学院 Gradient function coating with surface tension changed in gradient way and preparation method thereof
FR3004458A1 (en) 2013-04-11 2014-10-17 Rhodia Operations FRACTURING FLUIDS BASED ON ASSOCIATIVE POLYMERS AND SURFACTANTS LABILES
US9765169B2 (en) 2013-04-18 2017-09-19 Carnegie Mellon University Functionalized polymer hybrids
US9650463B2 (en) 2013-05-20 2017-05-16 Iowa State University Research Foundation, Inc. Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides
CA2949948A1 (en) 2013-05-22 2014-11-27 Triblue Corporation Methods of forming a polymer layer on a polymer surface
EP2824117A1 (en) 2013-07-09 2015-01-14 HILTI Aktiengesellschaft Reaction resin composition and its use
EP2824155A1 (en) 2013-07-09 2015-01-14 HILTI Aktiengesellschaft Reaction resin composition and its use
WO2015035342A2 (en) 2013-09-08 2015-03-12 Oligasis Llc Factor viii zwitterionic polymer conjugates
FR3011555A1 (en) 2013-10-04 2015-04-10 Rhodia Operations POLYMER SEQUENCES FOR FILTRAT CONTROL
JP2015117356A (en) 2013-11-18 2015-06-25 株式会社リコー Method for producing polymer, polymer product, particle, film, molded part and fiber
PL3094390T3 (en) 2014-01-16 2021-12-06 W.R. Grace & Co. - Conn. Affinity chromatography media and chromatography devices
EP2896637A1 (en) 2014-01-21 2015-07-22 Rhodia Operations Copolymer comprising units of type A deriving from carboxylic acid monomers and units of type B deriving from sulfonic acid monomers
CN103788266B (en) * 2014-02-12 2016-03-30 中国科学院长春应用化学研究所 A kind of method of atom transfer radical polymerization
JP6096381B2 (en) * 2014-04-08 2017-03-15 東洋ゴム工業株式会社 Rubber composition and pneumatic tire
WO2015160793A1 (en) 2014-04-14 2015-10-22 University Of Pittsburgh - Of The Commonwealth System Of Higher Education Biodegradable, thermally responsive injectable hydrogel for treatment of ischemic cardiomyopathy
JP6914189B2 (en) 2014-05-02 2021-08-04 ダブリュー・アール・グレース・アンド・カンパニー−コーンＷ Ｒ Ｇｒａｃｅ ＆ Ｃｏ−Ｃｏｎｎ Functionalized Carrier Materials and Methods for Making and Using Functionalized Carrier Materials
SG11201609358QA (en) 2014-05-21 2016-12-29 Univ Iowa State Res Found Poly(acrylated polyol) and method for making and using thereof as asphalt rubber modifiers, adhesives, fracking additives, or fracking fluids
CN106459256A (en) 2014-06-27 2017-02-22 汉高知识产权控股有限责任公司 Alkoxysilane-functionalized hydrocarbon compounds, intermediates thereof and methods of preparation thereof
US9840553B2 (en) 2014-06-28 2017-12-12 Kodiak Sciences Inc. Dual PDGF/VEGF antagonists
EP3164429A4 (en) 2014-07-03 2017-12-20 ATRP Solutions, Inc. Surfactant-compatible star macromolecules
EP3195846B1 (en) 2014-09-17 2020-01-01 Kuraray Noritake Dental Inc. Dental polymerizable composition
FR3027309B1 (en) 2014-10-17 2018-08-10 Rhodia Operations POLYFUNCTIONAL POLYMERS BASED ON PHOSPHONATE UNITS AND AMINE UNITS
CN107208076A (en) 2014-10-17 2017-09-26 科达制药 Butyrylcholine esterase amphoteric ion polymer conjugate
CN107075002B (en) * 2014-10-29 2019-11-19 日本瑞翁株式会社 The manufacturing method of conjugated diolefin polymer
WO2016070068A1 (en) 2014-10-31 2016-05-06 Ppg Industries Ohio, Inc. Resistive heating coatings containing graphene carbon particles and use of such coatings for low energy curing
EP3034573A1 (en) 2014-12-16 2016-06-22 ALLNEX AUSTRIA GmbH Flow modifier for coating compositions
EP3034520A1 (en) 2014-12-19 2016-06-22 HILTI Aktiengesellschaft Reaction resin composition and its use
EP3242899A4 (en) 2015-01-08 2018-07-04 Henkel IP & Holding GmbH Process for preparing high molecular weight polyacrylates having narrow polydispersity indices
US9982070B2 (en) 2015-01-12 2018-05-29 Carnegie Mellon University Aqueous ATRP in the presence of an activator regenerator
US20180051271A1 (en) 2015-02-10 2018-02-22 Carnegie Mellon University Non-aqueous enzyme-polymer conjugate solutions and related methods
US10608280B2 (en) 2015-03-09 2020-03-31 California Institute Of Technology Brush block copolymer electrolytes and electrocatalyst compositions
FR3034777A1 (en) 2015-04-07 2016-10-14 Rhodia Operations POLYMER SEQUENCES FOR FILTRAT CONTROL AND RHEOLOGY
FR3034768B1 (en) 2015-04-07 2017-05-05 Rhodia Operations POLYMER SEQUENCES FOR FILTRAT CONTROL
FR3034776A1 (en) 2015-04-07 2016-10-14 Rhodia Operations POLYMER SEQUENCES FOR FILTRAT CONTROL
US9650480B2 (en) 2015-04-15 2017-05-16 Ppg Industries Ohio, Inc. Curable film-forming compositions containing encapsulated catalyst components
EP3461878A3 (en) 2015-05-04 2019-08-07 Rhodia Operations Copolymers for protection of metals and/or lubrication
FR3037074B1 (en) 2015-06-03 2017-07-14 Rhodia Operations SUSPENSION AGENTS OBTAINED BY MICELLAR POLYMERIZATION
WO2016196906A1 (en) 2015-06-05 2016-12-08 W. R. Grace & Co.-Conn. Adsorbent bioprocessing clarification agents and methods of making and using the same
EP3325966B1 (en) 2015-07-20 2021-01-20 Sentilus Holdco, LLC Chips, detectors, and methods of making and using the same
MX2018001511A (en) 2015-08-04 2018-08-01 Univ Duke Genetically encoded intrinsically disordered stealth polymers for delivery and methods of using same.
FR3043083B1 (en) 2015-10-30 2019-04-19 Rhodia Operations SOLUBLE AMPHIPHILIC SEQUENCE POLYMERS IN HIGHLY SALT MEDIA
UA123505C2 (en) 2015-12-10 2021-04-14 Адама Махтешім Лтд. Polyelectrolyte-layer forming block copolymers and compositions and used thereof
WO2017103635A1 (en) 2015-12-16 2017-06-22 Rhodia Poliamida E Especialidades Ltda Emulsifier system for explosive emulsions
US11752213B2 (en) 2015-12-21 2023-09-12 Duke University Surfaces having reduced non-specific binding and antigenicity
EP3184499A1 (en) 2015-12-21 2017-06-28 HILTI Aktiengesellschaft Reaction resin composition, multi-component system and its use
EP3397276A4 (en) 2015-12-30 2019-12-18 Kodiak Sciences Inc. Antibodies and conjugates thereof
WO2017132137A1 (en) 2016-01-25 2017-08-03 Carnegie Mellon University Composite composition and modification of inorganic particles for use in composite compositions
EP3455266B1 (en) 2016-05-13 2020-10-28 Evonik Operations GmbH Graft copolymers based on polyolefin backbone and methacrylate side chains
US11467156B2 (en) 2016-06-01 2022-10-11 Duke University Nonfouling biosensors
WO2018007869A1 (en) 2016-07-02 2018-01-11 Rheomod De Mexico, S.A.P.I. De C.V. Grafted polymers
US11072674B2 (en) 2016-07-07 2021-07-27 Iowa State University Research Foundation, Inc. Multiblock copolymer and method of making thereof
WO2018031373A1 (en) 2016-08-12 2018-02-15 Iowa State University Research Foundation, Inc. Acrylated and acylated or acetalized polyol as a biobased substitute for hard, rigid thermoplastic and thermoplastic and thermoset materials
SG11201901623TA (en) 2016-08-31 2019-03-28 Evonik Oil Additives Gmbh Comb polymers for improving noack evaporation loss of engine oil formulations
US11590162B2 (en) 2016-10-07 2023-02-28 University of Pittsburgh—of the Commonwealth System of Higher Education Biodegradable, antioxidant, thermally responsive injectable hydrogel and uses therefor
US10982266B2 (en) 2016-11-03 2021-04-20 Carnegie Mellon University Nucleic acid-polymer conjugates for bright fluorescent tags
RU2019115085A (en) 2016-11-29 2021-01-11 Родиа Оперейшнс POLYMER SYSTEMS FOR PARTICLE DISPERSION
WO2018114673A1 (en) 2016-12-19 2018-06-28 Evonik Oil Additives Gmbh Lubricating oil composition comprising dispersant comb polymers
US20190358335A1 (en) 2017-01-12 2019-11-28 Alan J. Russell Stomach acid-stable and mucin-binding protein-polymer conjugates
WO2018132732A1 (en) 2017-01-12 2018-07-19 Duke University Genetically encoded lipid-polypeptide hybrid biomaterials that exhibit temperature triggered hierarchical self-assembly
WO2018132582A1 (en) 2017-01-12 2018-07-19 Carnegie Mellon University Surfactant assisted formation of a catalyst complex for emulsion atom transfer radical polymerization processes
JP7139335B2 (en) 2017-01-20 2022-09-20 イー インク カリフォルニア， エルエルシー Colored organic pigment and electrophoretic display medium containing the same
US11053356B2 (en) 2017-03-07 2021-07-06 California Institute Of Technology Control of polymer architectures by living ring-opening metathesis copolymerization
US9995987B1 (en) 2017-03-20 2018-06-12 E Ink Corporation Composite particles and method for making the same
FR3064641A1 (en) 2017-04-03 2018-10-05 Rhodia Operations ASSOCIATION FOR FILTRAT CONTROL AND GAS MIGRATION
WO2018213320A1 (en) 2017-05-15 2018-11-22 Duke University Recombinant production of hybrid lipid-biopolymer materials that self-assemble and encapsulate agents
EP3658168A4 (en) 2017-06-30 2021-07-14 Duke University Order and disorder as a design principle for stimuli-responsive biopolymer networks
WO2019012031A1 (en) 2017-07-14 2019-01-17 Evonik Oil Additives Gmbh Comb polymers comprising imide functionality
FR3070043B1 (en) 2017-08-09 2019-08-16 Rhodia Operations FORMULATION CONTAINING AN ASSOCIATIVE POLYMER
EP3450527B1 (en) 2017-09-04 2020-12-02 Evonik Operations GmbH New viscosity index improvers with defined molecular weight distributions
MX2020002862A (en) 2017-09-14 2020-11-06 Chemetall Gmbh Method for pretreating aluminum materials, particularly aluminum wheels.
CN111278934B (en) 2017-10-23 2022-04-12 巴斯夫欧洲公司 Aqueous silicone polymer emulsions
WO2019092036A1 (en) 2017-11-07 2019-05-16 Clariant Plastics & Coatings Ltd Dispersion agent for pigments in non-aqueous colourant preparations
US20190144686A1 (en) * 2017-11-10 2019-05-16 Aculon, Inc. Surface treatment compositions and coated articles prepared therefrom
ES2911491T3 (en) 2017-11-15 2022-05-19 Kuraray Co (Meth)acrylic block copolymer and active energy ray curable composition containing it
ES2801327T3 (en) 2017-12-13 2021-01-11 Evonik Operations Gmbh Viscosity index improver with improved shear strength and solubility after shear
EP3728512A1 (en) 2017-12-19 2020-10-28 Rhodia Operations Aqueous formulations of surfactants and associative polymers for the assisted recovery of petroleum
CN111492035B (en) 2017-12-20 2023-05-02 罗地亚经营管理公司 Polymer system for particle dispersion
AR114185A1 (en) 2018-01-23 2020-07-29 Adama Makhteshim Ltd SYNTHESIS OF 5-CHLORINE-2 - [(3,4,4-TRIFLUORO-3-BUTEN-1-IL) THIO] -THAZOLE
FR3079833B1 (en) 2018-04-10 2020-10-09 Rhodia Operations GELIFIED AQUEOUS COMPOSITION FOR OIL EXTRACTION
CN108251898A (en) * 2018-04-12 2018-07-06 江苏恒神股份有限公司 Polyacrylonitrile-based carbon fibre oil feeding system
WO2019204799A1 (en) 2018-04-20 2019-10-24 University Of Pittsburgh -Of The Commonwealth System Of Higher Education Cationic amphiphilic polymers for codelivery of hydrophobic agents and nucleic acids
JP7366011B2 (en) 2018-05-29 2023-10-20 株式会社 資生堂 Hair cosmetics containing block copolymers
CN112203635B (en) 2018-05-29 2024-01-16 株式会社资生堂 Inorganic particle dispersion for cosmetic containing block copolymer
WO2019246123A1 (en) 2018-06-18 2019-12-26 Cornell University Systems and methods for n-halamine-dopamine copolymers for high-performance, low-cost, and easy-to-apply antimicrobial coatings
FR3083238A1 (en) 2018-07-02 2020-01-03 Rhodia Operations PROGRESSIVE RELEASE OF POLYMER CHAINS IN A LIQUID MEDIUM
WO2020007926A1 (en) 2018-07-05 2020-01-09 Chemetall Gmbh Method for treating metallic surfaces with an acidic aqueous composition and a post rinsing composition to improve corrosion resistance
KR20210025650A (en) 2018-07-05 2021-03-09 케메탈 게엠베하 Method of treating metallic surfaces with acidic aqueous compositions to improve corrosion resistance
US11472894B2 (en) 2018-07-23 2022-10-18 Carnegie Mellon University Enzyme-assisted ATRP procedures
WO2020028806A1 (en) 2018-08-02 2020-02-06 Duke University Dual agonist fusion proteins
US20210332194A1 (en) 2018-08-27 2021-10-28 Basf Coatings Gmbh Pigment dispersant for coating
US11859106B2 (en) 2018-08-29 2024-01-02 Basf Coatings Gmbh Pigment dispersant
WO2020049132A1 (en) 2018-09-07 2020-03-12 Chemetall Gmbh Method for treating surfaces of aluminum containing substrates
CN112912542B (en) 2018-09-07 2023-06-02 凯密特尔有限责任公司 Method for treating surface of aluminum-containing substrate
KR20210093242A (en) 2018-10-08 2021-07-27 케메탈 게엠베하 Methods for NI-free phosphating of metal surfaces and compositions for use in such methods
CN112888809A (en) 2018-10-08 2021-06-01 凯密特尔有限责任公司 Method for nickel-free phosphating of metal surfaces and composition for use in such a method
CN112888761B (en) 2018-10-11 2023-05-02 罗地亚经营管理公司 Polymer dispersions obtained by controlled radical polymerization
JP7459087B2 (en) 2018-11-13 2024-04-01 エボニック オペレーションズ ゲーエムベーハー Random copolymers for use as base oils or lubricant additives
CN113195644B (en) * 2018-12-19 2023-01-24 汉高股份有限及两合公司 Coating against a substrate by in situ polymerization
EP3927660A1 (en) 2019-02-20 2021-12-29 PPG Industries Ohio Inc. Dispersions containing graphenic carbon nanoparticles and dispersant resins
KR20210134679A (en) 2019-02-28 2021-11-10 로디아 오퍼레이션스 Composition for high stabilization of emulsion
FR3093514A1 (en) 2019-03-05 2020-09-11 Rhodia Operations Suspension of associative polymers for the treatment of underground formations
BR102020004711A2 (en) 2019-03-11 2021-01-19 Evonik Operations Gmbh copolymers based on polyalkyl (meth) acrylate, additive composition, method of maintaining the kv100 at a given hths150, lubricating oil composition
WO2020182919A1 (en) 2019-03-12 2020-09-17 Rhodia Operations Stabilized friction reducer emulsions
WO2020190622A1 (en) 2019-03-15 2020-09-24 Rhodia Operations Polymer compositions and use of the same
MX2021011416A (en) 2019-03-20 2021-10-13 Evonik Operations Gmbh Polyalkyl(meth)acrylates for improving fuel economy, dispersancy and deposits performance.
US11733647B2 (en) * 2019-05-08 2023-08-22 Meta Platforms Technologies, Llc Light-activated controlled radical polymerization
US11512314B2 (en) 2019-07-12 2022-11-29 Duke University Amphiphilic polynucleotides
EP3778839B1 (en) 2019-08-13 2021-08-04 Evonik Operations GmbH Viscosity index improver with improved shear-resistance
EP4041312A4 (en) 2019-10-10 2023-12-20 Kodiak Sciences Inc. Methods of treating an eye disorder
WO2021113069A1 (en) 2019-12-02 2021-06-10 Solvay Usa Inc. Polymer dispersions for oilfield friction reduction
US11384311B2 (en) 2019-12-16 2022-07-12 Infineum International Limited High viscosity index comb polymer viscosity modifiers and methods of modifying lubricant viscosity using same
US11365273B2 (en) 2019-12-16 2022-06-21 Infineum International Limited High viscosity index comb polymer viscosity modifiers and methods of modifying lubricant viscosity using same
US11685874B2 (en) 2019-12-16 2023-06-27 Infineum International Limited High viscosity index comb polymer viscosity modifiers and methods of modifying lubricant viscosity using same
WO2021209349A1 (en) 2020-04-14 2021-10-21 Basf Se An amine-modified polymer, a controlled free radical polymerization for preparing the same and implementations thereof
EP3907269B1 (en) 2020-05-05 2023-05-03 Evonik Operations GmbH Hydrogenated linear polydiene copolymers as base stock or lubricant additives for lubricant compositions
EP4204467A1 (en) 2020-08-25 2023-07-05 Merck Patent GmbH Fluorine containing polymers
WO2022083963A1 (en) 2020-10-23 2022-04-28 Rhodia Operations Polymeric systems having enhanced viscosity and proppant transport properties
MX2023005739A (en) 2020-11-18 2023-05-25 Evonik Operations Gmbh Compressor oils with high viscosity index.
EP4060009B1 (en) 2021-03-19 2023-05-03 Evonik Operations GmbH Viscosity index improver and lubricant compositions thereof
AU2022273179A1 (en) 2021-05-12 2023-11-30 Basf Se Compositions, comprising platelet-shaped transition metal particles
FR3125296A1 (en) 2021-07-13 2023-01-20 Rhodia Operations Preparation of amphiphilic block polymers by reverse micellar radical polymerization
EP4119640B1 (en) 2021-07-16 2023-06-14 Evonik Operations GmbH Lubricant additive composition containing polyalkylmethacrylates
WO2023006322A1 (en) 2021-07-29 2023-02-02 Evonik Operations Gmbh Process for preparing low molecular weight polyacrylates and products thereof
WO2023072740A1 (en) 2021-10-26 2023-05-04 Basf Se A method for producing interference elements
WO2023091979A1 (en) 2021-11-22 2023-05-25 Ppg Industries Ohio, Inc. Acrylic materials and uses thereof
WO2023099635A1 (en) 2021-12-03 2023-06-08 Totalenergies Onetech Lubricant compositions
WO2023099631A1 (en) 2021-12-03 2023-06-08 Evonik Operations Gmbh Boronic ester modified polyalkyl(meth)acrylate polymers
WO2023099632A1 (en) 2021-12-03 2023-06-08 Evonik Operations Gmbh Boronic ester modified polyalkyl(meth)acrylate polymers
WO2023099630A1 (en) 2021-12-03 2023-06-08 Evonik Operations Gmbh Boronic ester modified polyalkyl(meth)acrylate polymers
WO2023099637A1 (en) 2021-12-03 2023-06-08 Totalenergies Onetech Lubricant compositions
WO2023099634A1 (en) 2021-12-03 2023-06-08 Totalenergies Onetech Lubricant compositions
WO2024033156A1 (en) 2022-08-08 2024-02-15 Evonik Operations Gmbh Polyalkyl (meth)acrylate-based polymers with improved low temperature properties
EP4321602A1 (en) 2022-08-10 2024-02-14 Evonik Operations GmbH Sulfur free poly alkyl(meth)acrylate copolymers as viscosity index improvers in lubricants

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3862978A (en) 1967-08-24 1975-01-28 Dow Chemical Co Catalytic synthesis of organic halogen compounds from an ethylenically unsaturated compound and a halogenated organic compound
US4145486A (en) 1974-08-29 1979-03-20 Mobil Oil Corporation Insoluble weak base exchange resin-metal compound complex
KR930000892B1 (en) * 1983-07-11 1993-02-11 커몬웰스 사이언티픽 앤드 인더스트리얼 리셔치 오가니제이숀 New polymerization process and polymers produced thereby
US5324879A (en) * 1985-12-03 1994-06-28 Commonwealth Scientific And Industrial Research Organisation Oligomerization process
US4728706A (en) * 1986-08-29 1988-03-01 E. I. Du Pont De Nemours And Company Titanium, zirconium- and hafnium containing initiators in the polymerization of acrylic monomers to "living" polymers
AU7895387A (en) 1986-09-29 1988-03-31 E.I. Du Pont De Nemours And Company Living polymers from unsaturated si, sn or ge initiators
US4940760A (en) * 1988-02-16 1990-07-10 E. I. Du Pont De Nemours And Company Group Transfer Polymerization process employing supported initiators
CA1326322C (en) * 1988-05-03 1994-01-18 Gabor Kaszas Uniform molecular weight polymers
US5169914A (en) 1988-05-03 1992-12-08 Edison Polymer Innovation Corporation Uniform molecular weight polymers
AU2295592A (en) * 1991-07-15 1993-02-23 Exxon Chemical Patents Inc. Living carbocationic polymerization process
US5405913A (en) * 1993-03-22 1995-04-11 The University Of Akron Free radical copper(II)-enolate polymerization initiators
US5312871A (en) * 1993-07-27 1994-05-17 Carnegie Mellon University Free radical polymerization process
US5530079A (en) * 1995-01-03 1996-06-25 Xerox Corporation Polymerization processes
FR2730240A1 (en) 1995-02-07 1996-08-09 Atochem Elf Sa STABILIZATION OF A POLYMER BY A STABLE FREE RADICAL
US5708102A (en) 1995-03-03 1998-01-13 E. I. Du Pont De Nemours And Company Living radical polymerization of vinyl monomers
US5763548A (en) 1995-03-31 1998-06-09 Carnegie-Mellon University (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
US5807937A (en) 1995-11-15 1998-09-15 Carnegie Mellon University Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties
JP3806475B2 (en) 1996-02-08 2006-08-09 株式会社カネカ Method for producing (meth) acrylic polymer having functional group at terminal
ATE207082T1 (en) 1996-06-12 2001-11-15 Univ Warwick POLYMERIZATION CATALYST AND PROCESS
DE69710130T2 (en) 1996-06-26 2002-08-29 Kaneka Corp Process for the production of vinyl polymers
US5789487A (en) * 1996-07-10 1998-08-04 Carnegie-Mellon University Preparation of novel homo- and copolymers using atom transfer radical polymerization
TW505665B (en) 1996-08-09 2002-10-11 Du Pont Process for polymerization of olefinic monomers
FR2752237B1 (en) 1996-08-12 1998-09-18 Atochem Elf Sa METHOD FOR CONTROLLED RADICAL POLYMERIZATION OR COPOLYMERIZATION OF (METH) ACRYLIC AND VINYLIC MONOMERS AND (CO) POLYMERS OBTAINED
FR2752238B1 (en) 1996-08-12 1998-09-18 Atochem Elf Sa METHOD FOR CONTROLLED RADICAL POLYMERIZATION OR COPOLYMERIZATION OF (METH) ACRYLIC AND VINYLIC MONOMERS AND (CO) POLYMERS OBTAINED
US5910549A (en) 1996-08-22 1999-06-08 Carnegie-Mellon University Method for preparation of alkoxyamines from nitroxyl radicals
FR2752845B1 (en) 1996-08-30 1998-10-30 Atochem Elf Sa PROCESS FOR CONTROLLED RADICAL (CO) POLYMERIZATION OF (METH) ACRYLIC AND VINYL MONOMERS IN THE PRESENCE OF A FE, RU OR BONE COMPLEX AND (CO) POLYMERS OBTAINED
WO1998020050A2 (en) 1996-11-01 1998-05-14 E.I. Du Pont De Nemours And Company Polymerization of vinyl monomers
FR2755441B1 (en) 1996-11-07 1998-12-24 Atochem Elf Sa PROCESS FOR CONTROLLED RADICAL (CO) POLYMERIZATION OF (METH) ACRYLIC, VINYLIC, VINYLIDENIC AND DIENE MONOMERS IN THE PRESENCE OF AN RH, CO OR IR COMPLEX
FR2757865B1 (en) 1996-12-26 1999-04-02 Atochem Elf Sa METHOD FOR CONTROLLED RADICAL POLYMERIZATION OR COPOLYMERIZATION OF (METH) ACRYLIC, VINYLIC, VINYLIDENIC AND DIENE MONOMERS AND (CO) POLYMERS OBTAINED
CN1165828A (en) 1997-03-13 1997-11-26 华东理工大学 Catalyst able to control polymerizing reaction and its application
US5886118C1 (en) 1997-04-14 2001-02-20 Univ Case Western Reserve Process for polymerizing acrylonitrile
US5773538A (en) 1997-07-16 1998-06-30 E. I. Du Pont De Nemours And Company Process for polymerization of olefinic monomers

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